I recently wanted to learn the basics to help my son and came across this article that made the most sense to me.
Pixel Art Tutorial: Basics
https://www.derekyu.com/makegames/pixelart.html
I have come across other articles that are similar in context but not as cleanly laid out.
The article doesn't go into the usage of software though. I think the design work flow, within software, would be greatly helpful in the understanding of achieving a great outcome. At least in a faster manner.
I hope that helps!
http://www.petesqbsite.com/sections/tutorials/tuts/tsugumo/
Is a classic in this aspiring pixel artist space.