In my mental model, the PDF is not a secret and can be stored anywhere -- encrypted, if desired, but it sounds like a public document.

The safe combination is a secret, and obviously belongs in secret storage.

In this specific example, if I had trouble remembering whether the first number of the combination was reached via cw or ccw rotations, I'd include that in the secret, e.g. "cw34-12-22-45".

(Some safe combinations require multiple rotations. I unintentionally became the owner of one that is something like "cw3x34-ccw2x12-cw5x22-ccw2x45". I still can't open it actually, but that pattern is what the Internet tells me. :)