I looked this up on Wikipedia. It seems that he was working as an instructor (not a professor) of chemistry; since he was making more money as a writer during that time, he slowed down or stopped his research. Doesn’t seem to have been an intentional choice so much as how things happened to turn out.
I've read his biography. It was definitely intentional - and of course making a living by writing was a big factor. But he just didn't like the academic environment or his colleagues.
> he was working as an instructor (not a professor)
No he eventually became a full professor too.
"He began work in 1949 with a $5,000 salary(equivalent to $68,000 in 2025), maintaining this position for several years. By 1952, however, he was making more money as a writer than from the university, and he eventually stopped doing research, confining his university role to lecturing students.[g] In 1955, he was promoted to tenured associate professor. In December 1957, Asimov was dismissed from his teaching post, with effect from June 30, 1958, due to his lack of research. After a struggle over two years, he reached an agreement with the university that he would keep his title and give the opening lecture each year for a biochemistry class. On October 18, 1979, the university honored his writing by promoting him to full professor of biochemistry."