The Jaguar catalog was mostly meh, but there were a few gems that I really enjoyed (Aliens vs Predator, Doom, Wolf 3d, Iron Soldier, and Tempest 2000). AvP alone was worth the price of the system.
I was a proud Turbo DUO owner. It had some fantastic multiplayer games, especially 5-player Bomberman. That got a lot of play, including tournaments at work. Dungeon Explorer is another one we played through multiple times.
FYI, Sega Saturn has 10 player bomberman. It's insanely fun.
I have to push back on that a bit.
I played through the campaign for Alien vs Predator for both the Space Marine and the Alien campaigns in BigPEmu, and I really think it's a mediocre-at-best Wolf 3D clone. If it had been released on anything besides the Jag, then I think it would be, at best, relegated to the annals of mediocrity like the dozens of other Wolfenstein 3D knock offs. I wanted to like it because I love the first two Alien movies, but I really do not think it holds up compared to most FPS games, even at the time.
I haven't fully gone through the Turbo CD catalog yet, but I did play through It Came From Outer space and that was a blast in a "so bad it's good" kind of way.