Dave Jones used to have a series of "Why user space sucks" Linux kernel conference talks with many such examples, usually with dumb and redundant system calls.

However as someone who looks a lot at instruction traces I could probably write on e on why Linux kernel code sucks too. One of my current pet peeves is the way Linux walks bitmasks of CPU bits, which is a reasonably common operation. Due to a chain of unfortunate changes and decisions it currently needs 16+ instructions to find the next bit for something which the x86 instruction set has a single instruction. Of course that is so big that it is even outlined, adding even more overhead.